5x5 to 7x7: centres, edges and parity
Reduction and Yau on the bigger cubes: centres in bars, freeslice edge pairing, the last edges and the parities.
Bigger cubes are solved by reduction, as the 4x4: build the centres, pair each edge's pieces, then solve the cube as a 3x3 with outer turns. Odd cubes (5x5, 7x7) have a fixed centre piece on each face and a fixed middle edge piece in each edge, so the colour scheme is given and each edge is paired around its middle piece; even cubes (6x6) behave like the 4x4 and have its parities.
Centres on bigger cubes
Centres are built from bars as wide as the centre, joined row by row: first two opposite centres, then the side centres around them. On the 6x6 and 7x7 the bars are longer and the order matters more, so solvers plan a whole bar at a time. The last two centres share their pieces, and their cases are the L2C sets.
Edge pairing and freeslice
Freeslice pairs the edges with the slices left out of line: rather than restoring the centres after each pairing, keep working with the slice turned and restore it only when the last edges are done. It is common among the fastest 5x5 and bigger-cube solvers. Pairing ends with two edges left, the L2E sets.
Last two edges and edge parity
On odd cubes the last two edges can show edge parity: a middle piece flipped against its wings, a position no 3x3 has, fixed by the parity cases of the L2E set. Even cubes add the 4x4's parities, a single flipped dedge or two swapped, for the 3x3 stage.
L2E
15 cases · Pair the last edges, edge parity included: 15 cases.
L2E
3 cases · Pair the last edges, parity included: 3 cases.
Yau on 5x5 and up
Yau's order works on every size: two opposite centres, three cross edges built and placed, the last four centres, then the remaining edges and the 3x3 stage. It has spread from the 4x4 to the 6x6 and 7x7, where building the cross edges while the cube still has room saves time in the crowded last stages. Hoya's order (the cross before the last two centres) is also used on the 5x5.
Even-cube parity
The 6x6, like the 4x4, has no fixed centres or middle edges, so a reduced 6x6 can show OLL and PLL parity. It is fixed with parity algorithms like the 4x4's, turning the inner slices.
8x8 and bigger
Cubes beyond the 7x7 are solved the same way, with longer bars and more edge pieces per edge: even sizes behave like the 6x6 and odd sizes like the 7x7. No algorithm sets are published for them; the L2C and L2E ideas carry over, applied to the inner slices that differ.
The 3x3 stage
Once reduced, the cube is solved with outer turns as a 3x3, with the 3x3's methods and algorithms. On the 7x7 the 3x3 stage is a small share of the solve; on the 5x5 it is larger, and a good last-layer system pays off.
5x5 to 7x7: centres, edges and parity: the whole walkthrough
Centres on bigger cubes
Edge pairing and freeslice
Last two edges and edge parity
Yau on 5x5 and up
Even-cube parity
8x8 and bigger
The 3x3 stage
All systems